The two of the favourites for the Confederations Cup do battle in Kazan tonight.
Chile and Germany will go head-to-head after opening their respective campaigns with wins last time out.
Alexis Sanchez is set to return to Chile's starting line-up for the Group B clash.
The Arsenal star was on the bench for the encounter with Cameroon due to an ankle problem but set up Arturo Vidal's opener as the south American side won 2-0.
World champions Germany were far from their best as they edged past Australia.
Sanchez's club mate Shkodran Mustafi is expected to keep his place while Liverpool midfielder Emre Can could come in.
Kick-off in Kazan is at 7pm.
Germany starting XI: ter Stegen, Mustafi, Hector, Ginter, Draxler, Goretzka, Stindl, Can, Sule, Kimmich, Rudy
Chile starting XI: Herrera, Isla, Medel, Beausejour, Jara, Diaz, Aranguiz, Hernandez, Vidal, Vargas, Sanchez
Australia vs Cameroon
Mark Milligan’s second-half penalty meant Australia and Cameroon had to settle for a 1-1 draw in the Confederations Cup in St Petersburg.
Both sides were chasing a win after losing their opening fixtures in Group B, but an end-to-end match saw the two teams cancel each other out and effectively end their chances of progression.
Andre Anguissa opened the scoring in first-half stoppage-time as he raced onto a long ball from defender Michael Ngadeu-Ngadjui which exposed Australia’s high back-line before poking the ball over the head of onrushing goalkeeper Mathew Ryan.
The lead was short-lived, however, as Alex Gersbach was brought down inside the area and Milligan despatched the spot-kick with precision after the video assistant referee (VAR) had ruled in favour of Australia.
Alexis Sanchez warms up
Alexis Sanchez is currently going through his paces in the warm up.
The striker is well and truly in the shop window - with Bayern Munich and Manchester City hovering.
Sanchez’s Arsenal contract runs out at the end of next season.
Although his priority tonight is to ensure Chile progress in the Confederations Cup.
Chile record
Alexis Sanchez will draw level with Claudio Bravo as the most capped Chilean.
Once the Arsenal striker steps onto the pitch it will be his 112 appearance on the international stage.
With plenty of football in both player’s legs you will image it will stay neck and neck for a while.
Manchester City keeper Bravo, who is currently injured, won’t get close to Sanchez’s 37 goals - you wouldn’t think.
Tonight’s game will be staged at the Kazan Arena, which is funnily enough in Kazan.
Portugal drew with Mexico in the only other game held there so far.
Six World Cup fixtures will be played at the Kazan Arena next summer.
Alexis Sanchez starts
The biggest news from the team sheet is that Alexis Sanchez starts for Chile.
The Arsenal man started the first game of the tournament against Cameroon on the bench - due to an ankle injury.
He came on in the second half and created both goals in that 2-0 win.
Sanchez, who has arrived at the stadium as you can see in the below snap, will be up against current club team mate Mustafi.
Will they still be playing together next season though?
Welcome
No wonder Alexis Sanchez is a man in such demand.
Shkodran Mustafi has hailed rare and world class talent Sanchez in a glowing tribute to his Arsenal team-mate. And as he revealed just how difficult it is to stop one of football’s most feared attackers, Mustafi underlined just why some of Europe’s biggest clubs are jostling to sign him but why he is also so desperate for Sanchez to stay at Arsenal.
Manchester City, Chelsea and Bayern Munich are among the clubs battling it out to try to prise Sanchez away from the Gunners.
At the same time, the North Londoners are trying to persuade him that his future lies at the Emirates and to sign the new deal on the table, which is worth more than £275,000-a-week .
Defender Mustafi said: “Of course I hope he stays. It would be a pity to lose him.
“Alexis is an exceptional player — for me one of the best in world football. I have experienced few players who are as hungry as him.
“He is nimble, agile, but despite his size very sturdy, and can dribble past players. Alexis is a complete player.”
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